Таблица I-Б-5: Моля, посочете методите за идентифициране на PFOS, нейните соли, PFOSF или нейните деривати (PFOS) в изделията, които Вашата компания рециклира? Добавете допълнителни редове, ако е необходимо.
Вид изделие, съдържащо PFOS, нейните соли, PFOSF или нейните деривати (PFOS)
|
Метод за идентифициране
|
Описание (по етикет, по ИЛБ, по данни на производителя/вносителя, чрез анализи и т.н.)
|
1.
|
|
|
2.
|
|
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3.
|
|
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Таблица II-Б-6: Моля, посочете използваните от Вас методи за екологосъобразно депониране, в т.ч. обезвреждане на изделия, съдържащи PFOS, нейните соли, PFOSF или нейните деривати (PFOS) (операции D). Добавете допълнителни редове, ако е необходимо.
Методи за екологосъобразно депониране или обезвреждане на изделия или части от изделия, съдържащи PFOS
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Описание
|
1.
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|
2.
|
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3.
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Част IІ – Информация относно алтернативи за заместване на перфлуороктан сулфонова киселина (PFOS), нейните соли, перфлуороктан сулфонил флуорид (PFOSF) и PFOS деривати в различните типове употреби и пиложения
ЧАСТ ІІ – ПОДРОБНИ ВЪПРОСИ
ІІ-1: Моля да предоставите информация за алтернативните химични вещества или смеси, използвани за заместване на перфлуорооктан сулфоновата киселина (PFOS) и нейните деривати в изделията/смесите, които пускате на пазара или изнасяте**. (виж Приложение 2)
** Моля да имате в предвид, че за употребите, изброени в лявата колона PFOS и нейните деривати са забранени, ако концентрацията им надвишава 0.1 тегл.% (1000 g/kg).За употребите, изброени в дясната колона,производството и пускането на пазара е разрешено.
Ако предлагате на пазара повече от едно изделие или смес от изброените по-долу употреби, моля да копирате цялата таблица и предоставите информация за всяка алтернатива за всяка употреба по отделно.
Информация относно алтернативи на PFOS и нейните деривати в различни употреби и приложения***:
|
1.Описание на алтернативите
(хим.наименование, CAS №, търговска марка, производител/вносител)
|
|
2. Употребени количества на година (по години), кг, внос (държава)
|
|
3. Тип употреба
|
Импрегниран текстил, текстилни изделия (тапицирани мебели, обувки) и защитни облекла
Килими, мокети
Кожа и кожени изделия (кожени мебели)
Импрегниране на хартия/картони за опаковки
Каучук и пластмаси
Бои, лакове
Препарати за почистване, излъскване и полиране на коли и подове
Вакси за излъскване на ски
Пожарогасителни пени
Електрически и електронни части за цифрови камери, мобилни телефони, цветни принтери и копирни машини, скенери, сателитно-комуникационна техника, радарни системи и др.
Нефтопреработвателна и минна промишленост
Защитни покрития
Добавки за печатни мастила за цветни принтери и копирни машини
Други
|
До 26 август 2015 г. — мокрещи агенти, използвани в контролирани системи за нанасяне на галванични покрития;
Фоторезисти или антирефлектиращи покрития за фотолитографски процеси
Фотографски покрития, нанасяни върху филми, хартия или печатни платки
Вещества, потискащи образуването на суспензия при недекоративно твърдо хромиране с хром (VI) в системи със затворен цикъл;
Хидравлични флуиди за авиацията
|
4. Физико-химични свойства от ИЛБ
|
|
5. Наличност на пазара
|
|
6. Пазарна и ценова достъпност
|
|
7. Класификация според Глобалната хармонизирана система (GHS)
|
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8. Друга информация
|
|
*** Забележка
-
Описание на алтернативата:
-
За алтернативният химичен продукт, моля посочете химичното наименование, CAS №, търговско наименование, производител.
-
За алтернативният химичен продукт, моля посочете физико-химичните свойства като парно налягане, коефициент на разделяне октанол/вода (log Kow);
-
Количества на година:
Моля посочете, ако е възможно, количествата, употребени на година .
-
Тип употреба :
Отбележете със знак “х” типа на употребата. Ако употребите са повече от една копирайте цялата таблица и попълнете за всяка отделна алтернатива.
-
Физико-химични свойства: Посочете физико-химичните свойства от ИЛБ
-
Наличност:
Отнася се до това, дали алтернативата е налична на пазара. Информация за производители и търговци, ако Ви е известна, също трябва да бъде включена.
-
Пазарна и ценова достъпност
Моля, посочете дали алтернативния продукт е лесно достъпен на пазара и ценово-изгоден за Вашата компания.
-
Класификация според Глобалната хармонизирана система (GHS):
Моля, посочете, класификацията на алтернативното съединение съгласно Приложение VІ на Регламент (ЕО) 1272/2008 (CLP) , Таблица 3.1, в която са записани веществата, класифицирани в съответствие с критериите на CLP Регламента и Таблица 3.2, в която са записани веществата, класифицирани и етикетирани в съответствие с критериите в Директива 67/548/EИО за опасните вещества /DSD/
-
Друга информация:
Моля посочете, ако досега сте използвали PFOS и някои от нейните деривати (виж Приложение 1), кога сте преминали към алтернативния продукт при Вашето производството.
____________________
Приложения с помощна информация за попълване на Въпросника
Приложение № 1 : Категории изделия, съдържащи PFOS, нейните соли, PFOSF или нейните деривати (PFOS) или процеси, използващи такива химикали като междинен продукт
-
Изделия
-
Импрегнирани опаковки (хартия/картон)
-
Импрегниран текстил, текстилни изделия (тапицерии, дамаски) и защитни облекла
-
Килими и мокети
-
Кожа и кожени изделия (кожени мебели, обувки, облекло)
-
Някои медицински прибори [като покрития на основата на съполимери на етилен тетрафлуоретилен (ETFE) и производство на рентгено-контрастен ETFE, in-vitro диагностична медицинска апаратура и CCD цветни филтри];
-
Електрически и електронни части за цифрови камери, мобилни телефони, цветни принтери и копирни машини, скенери, сателитно-комуникационна техника, радарни системи и др.
-
Някои видове каучуци и пластмаси
-
Защитни покрития и добавки за покрития;
-
Пожарогасителни пени
-
Хидравлични флуиди за авиацията
-
Индустриални процеси
-
Мокрещи агенти, използвани в контролирани системи за нанасяне на галванични покрития
-
Галванични покрития на метали (твърдо и декоративно галванизиране);
-
Агент за байцване на полупроводници и керамични филтри;
-
Фото-маски за полупроводници и течно-кристални дисплеи (LCD);
-
Фоторезисти или антирефлектиращи покрития за фотолитографски процеси;
-
Фотопроявители;
-
Фоторезисти или антирефлектиращи покрития при производството на полупроводници;
-
Фотографски покрития, нанасяни върху филми, хартия или печатни платки;
-
Вещества, потискащи образуването на суспензия при недекоративно твърдо хромиране с хром (VI) в системи със затворен цикъл;
-
Нефтодобив;
-
Миннодобивна промишленост.
-
Потребителски продукти
-
Препарати за почистване, излъскване и полиране на коли и подове;
-
Вакси за ски;
-
ПАВ, бои и лакове
Приложение № 2: PFOS и и нейните дериватите
Таблица 1:PFOS и дериватите, включени в Приложение Б на Стокхолмската конвенция
PFOS и деривати
|
Съкращение
|
CAS №
|
Perfluorooctane sulfonic acid
|
(PFOS)
|
1763-23-1
|
Potassium perfluorooctane sulfonate
|
(PFOS-K)
|
2795-39-3
|
Lithium perfluorooctane sulfonate
|
(PFOS-Li)
|
29457-72-5
|
Ammonium perfluorooctane sulfonate
|
(PFOS-NH4)
|
29081-56-9
|
Diethanolammonium perfluorooctane sulfonate
|
(PFOS-DEA)
|
70225-14-8
|
Perfluorooctane sulfonyl fluoride
|
(PFOS-F)
|
307-35-7
|
Tetraethylammonium perfluorooctane sulfonate
|
|
56773-42-3
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Di(decyl)di(methyl)ammonium perfluorooctane sulfonate
|
|
2551099-16-8
|
Таблица 2: Примери на PFOS деривати, непосочени в Приложение Б на Стокхолмската конвенция
Химично наименование
|
Съкращение
|
CAS №
|
Perfluorooctane sulfonamide
|
PFOSA
|
754-91-6
|
N-Methyl perfluorooctane sulfonamide
|
MeFOSA
|
31506-32-8
|
N-Methyl perfluorooctane sulfonamidoethanol
|
MeFOSE
|
2448-09-7
|
N-Methyl perfluorooctane sulfonamidoethyl acrylate
|
MeFOSEA
|
25268-77-3
|
Ammonium bis[2-N-ethyl perfluorooctane sulfonamidoethyl] phosphate1
|
|
30381-98-7
|
N-Ethyl perfluorooctane sulfonamide (sulfluramid)
|
EtFOSA
|
4151-50-2
|
N-Ethyl perfluorooctane sulfonamidoethanol
|
EtFOSE
|
1691-99-2
|
N-Ethyl perfluorooctane sulfonamidoethyl acrylate
|
EtFOSEA
|
432-82-5
|
Di[N-ethyl perfluorooctane sulfonamidoethyl] phosphate
|
EtFOSEP
|
67969-69-1
|
3-[[(Heptadecafluorooctyl)- sulfonyl]amino]-N,N,N-trimethyl-1-propanaminium iodide/perfluorooctyl sulfonyl quaternary ammonium iodide
|
Fluorotenside-134
|
1652-63-7
|
Potassium N-ethyl-N-[(heptadecafluorooctyl) sulfonyl] glycinate
|
|
2991-51-7
|
N-Ethyl-N-[3-(trimethoxysilyl)propyl] perfluorooctane sulfonamide
|
|
61660-12-6
|
Таблица 3: Списък на съединения на 96 PFOS-деривати, които се разграждат до PFOS в околната среда
№
|
CAS №
|
PFOS и нейните деривати
|
1
|
307-35-7
|
1-Octanesulphonyl fluoride, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
2
|
376-14-7
|
2-Propenoic acid, 2-methyl-, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester
|
3
|
383-07-3
|
2-Propenoic acid, 2-[butyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester
|
4
|
423-82-5
|
2-Propenoic acid, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester
|
5
|
423-86-9
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-2-propenyl-
|
6
|
754-91-6
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
7
|
1652-63-7
|
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl]amino]-N,N,N-trimethyl-, iodide
|
8
|
1691-99-2
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-
|
9
|
1763-23-1
|
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
10
|
1869-77-8
|
Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-, ethyl ester
|
11
|
2250-98-8
|
1-Octanesulphonamide, N,N',N''- [phosphinylidynetris(oxy-2,1-ethanediyl)]tris[N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
12
|
2263-09-4
|
1-Octanesulphonamide, N-butyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-
|
13
|
2795-39-3
|
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, potassium salt
|
14
|
2991-50-6
|
Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-
|
15
|
2991-51-7
|
Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-, potassium salt
|
16
|
3820-83-5
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[2-(phosphonooxy)ethyl]-
|
17
|
3871-50-9
|
Glycine, N-ethyl-N-[(heptadecafluorooctyl)sulphonyl]-, sodium salt
|
18
|
4151-50-2
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
19
|
13417-01-1
|
1-Octanesulphonamide, N-[3-(dimethylamino)propyl]-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
20
|
14650-24-9
|
2-Propenoic acid, 2-methyl-, 2- [[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl ester
|
21
|
24448-09-7
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-N-methyl-
|
22
|
24924-36-5
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-2-propenyl-
|
23
|
25268-77-3
|
2-Propenoic acid, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl ester
|
24
|
29081-56-9
|
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ammonium salt
|
25
|
29117-08-6
|
Poly(oxy-1,2-ethanediyl), .alpha.-[2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl]-.omega.-hydroxy-
|
26
|
29457-72-5
|
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, lithium salt
|
27
|
30295-51-3
|
1-Octanesulphonamide, N-[3-(dimethyloxidoamino)propyl]-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-
|
28
|
30381-98-7
|
1-Octanesulphonamide, N,N'-[phosphinicobis(oxy-2,1-ethanediyl)]bis[N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ammonium salt
|
29
|
31506-32-8
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-methyl-
|
30
|
38006-74-5
|
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl]amino]-N,N’,N’’-trimethyl-, chloride
|
31
|
50598-29-3
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(phenylmethyl)-
|
32
|
52550-45-5
|
Poly(oxy-1,2-ethanediyl), a-[2-[[(heptadecafluorooctyl)sulphonyl]propylamino]ethyl]-? -hydroxy-
|
33
|
56773-42-3
|
Ethanaminium, N,N’,N’’-triethyl-, salt with 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-1-octanesulphonic acid (1:1)
|
34
|
57589-85-2
|
Benzoic acid, 2,3,4,5-tetrachloro-6-[[[3- [[(heptadecafluorooctyl)sulphonyl]oxy]phenyl]amino]carbonyl]-, monopotassium salt
|
35
|
58920-31-3
|
2-Propenoic acid, 4-[[(heptadecafluorooctyl)sulphonyl]methylamino]butyl ester
|
36
|
61577-14-8
|
2-Propenoic acid, 2-methyl-, 4-[[(heptadecafluorooctyl)sulphonyl]methylamino]butyl ester
|
37
|
61660-12-6
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[3-(trimethoxysilyl)propyl]-
|
38
|
67939-42-8
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[3-(trichlorosilyl)propyl]-
|
39
|
67969-69-1
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-[2-(phosphonooxy)ethyl]-, diammonium salt
|
40
|
67939-88-2
|
1-Octanesulphonamide, N-[3-(dimethylamino)propyl]- 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, monohydrochloride
|
41
|
68081-83-4
|
Carbamic acid, (4-methyl-1,3-phenylene)bis-, bis[2-[ethyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl] ester
|
42
|
68298-11-3
|
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl](3-sulphopropyl)amino]-N-(2-hydroxyethyl)-N,N-dimethyl-, hydroxide, inner salt
|
43
|
68329-56-6
|
2-Propenoic acid, eicosyl ester, polymer with 2-[[(heptadecafluorooctyl)sulphonyl] methylamino]ethyl 2-propenoate, hexadecyl 2-propenoate, 2-[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2-[methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-propenoate, 2-[methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-propenoate, 2-[methyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-propenoate and octadecyl 2-propenoate
|
44
|
68239-73-6
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(4-hydroxybutyl)-N-methyl-
|
45
|
68310-75-8
|
1-Propanaminium, 3-[[(heptadecafluorooctyl)sulphonyl]amino]-N,N’,N’’-trimethyl-, iodide, ammonium salt
|
46
|
68541-80-0
|
2-Propenoic acid, polymer with 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate and octadecyl 2-propenoate
|
47
|
68555-90-8
|
2-Propenoic acid, butyl ester,polymer with 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl 2-propenoate, 2-[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2-[methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-propenoate, 2-[methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-propenoate and 2-[methyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-propenoate
|
48
|
68555-91-9
|
2-Propenoic acid, 2-methyl-, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester, polymer with 2-[ethyl[(nonafluorobutyl)sulphonyl]amino] ethyl 2-methyl-
2-propenoate, 2-[ethyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2-[ethyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-methyl-2-
propenoate, 2- [ethyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate and octadecyl 2-methyl-2-propenoate
|
49
|
68555-92-0
|
2-Propenoic acid, 2-methyl-, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl ester, polymer with 2- [methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-
methyl-2-propenoate, 2- [methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2- [methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-
methyl-2-propenoate, 2- [methyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate and octadecyl 2-methyl-2-propenoate
|
50
|
68608-14-0
|
Sulphonamides, C4-8-alkane, perfluoro, N-ethyl-N-(hydroxyethyl), reaction products with 1,1'-methylenebis[4-isocyanatobenzene]
|
51
|
68649-26-3
|
1-Octanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-, reaction products with N-ethyl-1,1,2,2,3,3,4,4,4-nonafluoro-N-(2-hydroxyethyl)-1-butanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,7-pentadecafluoro-N-(2-hydroxyethyl)- 1-heptanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluoro-N-(2-hydroxyethyl)-1-hexanesulphonamide, N-ethyl-1,1,2,2,3,3,4,4,5,5,5-undecafluoro-N-(2-hydroxyethyl)-1-pentanesulphonamide, polymethylenepolyphenyleneisocyanate and stearyl alc.
|
52
|
68867-60-7
|
2-Propenoic acid, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl ester, polymer with 2-[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2-
[methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-propenoate, 2- [methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-propenoate, 2-
[methyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-propenoate and.alpha.-(1-oxo-2-propenyl)-.omega.-methoxypoly(oxy-1,2-ethanediyl)
|
53
|
68877-32-7
|
2-Propenoic acid, 2-methyl-, 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl ester, polymer with 2-[ethyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2-[ethyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2-[ethyl[(tridecafluoro-hexyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2-[ethyl[(undecafluoro-pentyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate and 2-methyl-1,3-butadiene
|
54
|
68891-96-3
|
Chromium, diaquatetrachloro[.mu.-[N-ethyl-N- [(heptadecafluorooctyl)sulphonyl] glycinato-.kappa.O:.kappa.O']]-.mu.-hydroxybis(2-methylpropanol)di-
|
55
|
68909-15-9
|
2-Propenoic acid, eicosyl ester, polymers with branched octylacrylate, 2- [[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl acrylate, 2-[methyl [(nonafluorobutyl)sulphonyl]amino]ethyl acrylate, 2- [methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl acrylate, 2-[methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl acrylate, 2- [methyl[(undecafluoropentyl)sulphonyl]amino]ethyl acrylate, polyethylene glycol acrylate Me ether and stearyl acrylate
|
56
|
68958-61-2
|
Poly(oxy-1,2-ethanediyl), .alpha.-[2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl]-.omega.-methoxy-
|
57
|
70225-14-8
|
1-Octanesulphonic acid, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, compd. with 2,2'-iminobis[ethanol] (1:1)
|
58
|
70776-36-2
|
2-Propenoic acid, 2-methyl-, octadecyl ester, polymer with 1,1-dichloroethene, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl 2-propenoate, N-
(hydroxymethyl)-2-propenamide, 2-[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2-[methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-
propenoate, 2-[methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-propenoate and 2-[methyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-propenoate
|
59
|
71463-78-0
|
Phosphonic acid, [3-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]propyl]-
|
60
|
71463-80-4
|
Phosphonic acid, [3-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]propyl]-, diethyl ester
|
61
|
71487-20-2
|
2-Propenoic acid, 2-methyl-, methyl ester, polymer with ethenylbenzene, 2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl 2-propenoate, 2-
[methyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-propenoate, 2- [methyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-propenoate, 2-
[methyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-propenoate, 2- [methyl[(undecafluoropentyl)sulphonyl]amino]ethyl 2-propenoate and 2-propenoic acid
|
62
|
91081-99-1
|
Sulphonamides, C4-8-alkane, perfluoro, N-(hydroxyethyl)-N-methyl, reaction products with epichlorohydrin, adipates (esters)
|
63
|
92265-81-1
|
Ethanaminium, N,N,N-trimethyl-2-[(2-methyl-1-oxo-2-propenyl)oxy]-, chloride, polymer with 2-ethoxyethyl 2-propenoate, 2-[[(heptadecafluorooctyl)sulphonyl] methylamino]ethyl 2-propenoate and oxiranylmethyl 2-methyl-2-propenoate
|
64
|
94133-90-1
|
1-Propanesulphonic acid, 3-[[3-(dimethylamino)propyl][(heptadecafluorooctyl) sulphonyl]amino]-2-hydroxy-, monosodium salt
|
65
|
94313-84-5
|
Carbamic acid, [5-[[[2-[[(heptadecafluorooctyl)sulphonyl]methylamino]ethoxy]carbonyl]amino]-2-methylphenyl]-, 9-octadecenyl ester, (Z)-
|
66
|
98999-57-6
|
Sulphonamides, C7-8-alkane, perfluoro, N-methyl-N-[2-[(1-oxo-2-propenyl)oxy]ethyl], polymers with 2-ethoxyethyl acrylate, glycidyl methacrylate and N,N,N-trimethyl-2-[(2-methyl-1-oxo-2-propenyl)oxy]ethanaminium chloride
|
67
|
127133-66-8
|
2-Propenoic acid, 2-methyl-, polymers with Bu methacrylate, lauryl methacrylate and 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl methacrylate
|
68
|
129813-71-4
|
Sulphonamides, C4-8-alkane, perfluoro, N-methyl-N-(oxiranylmethyl)
|
69
|
148240-78-2
|
Fatty acids, C18-unsatd., trimers, 2-[[heptadecafluorooctyl)sulphonyl]methylamino]ethyl esters
|
70
|
148684-79-1
|
Sulphonamides, C4-8-alkane, perfluoro, N-(hydroxyethyl)-N-methyl, reaction products with 1,6-diisocyanatohexane homopolymer and ethylene glycol
|
71
|
160901-25-7
|
Sulphonamides, C4-8-alkane, perfluoro, N-ethyl-N-(hydroxyethyl), reaction products with 2-ethyl-1-hexanol and polymethylenepolyphenylene isocyanate
|
72
|
178094-69-4
|
1-Octanesulphonamide, N-[3-(dimethyloxidoamino)propyl]-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-,potassium salt
|
73
|
178535-22-3
|
Sulphonamides, C4-8-alkane, perfluoro, N-ethyl-N-(hydroxyethyl)-, polymers with 1,1'-methylenebis[4-isocyanatobenzene] and polymethylenepolyphenylene isocyanate, 2-ethylhexyl esters, Me Et ketone oxime-blocked
|
74
|
182700-90-9
|
1-Octanesulphonamide, 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-methyl-, reaction products with benzene-chlorine-sulphur chloride (S2Cl2) reaction products chlorides
|
75
|
L-92-0151
|
2-Propenoic acid, 2-methyl-, butyl ester, polymer with 2-[ethyl[(heptadecafluorooctyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2-[ethyl[(nonafluorobutyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2- [ethyl[(pentadecafluoroheptyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate, 2-[ethyl[(tridecafluorohexyl)sulphonyl]amino]ethyl 2-methyl-2-propenoate and 2-propenoic acid
|
76
|
P-94-2205
|
Polymethylenepolyphenylene isocyanate and bis(4-NCO-phenyl)methane reaction products with 2-ethyl-1-hexanol, 2-butanone, oxime, N-ethyl-N-(2-hydroxyethyl)-1-C4-C8perfluoroalkanesulphonamide
|
77
|
192662-29-6
|
Sulphonamides, C4-8-alkane, perfluoro, N-[3-(dimethylamino)propyl], reaction products with acrylic acid
|
78
|
251099-16-8
|
1-Decanaminium, N-decyl-N,N-dimethyl-, salt with 1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-1-octanesulphonic acid (1:1)
|
79
|
306973-46-6
|
Fatty acids, linseed-oil, dimers, 2- [[(heptadecafluorooctyl)sulphonyl]methylamino]ethyl esters
|
80
|
306973-47-7
|
Sulphonamides, C4-8-alkane, perfluoro, N-(hydroxyethyl)-N-methyl, reaction products with 12-hydroxystearic acid and 2,4-TDI, ammonium salts
|
81
|
306974-19-6
|
Sulphonamides, C4-8-alkane, perfluoro, N-methyl-N-[(3-octadecyl-2-oxo-5-oxazolidinyl)methyl]
|
82
|
306974-28-7
|
Siloxanes and Silicones, di-Me, mono[3-[(2-methyl-1-oxo-2-propenyl)oxy]propylgroup] -terminated, polymers with 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate and stearyl methacrylate
|
83
|
306974-45-8
|
Sulphonic acids, C6-8-alkane, perfluoro, compounds with polyethylene-polypropylene glycol bis(2-aminopropyl) ether
|
84
|
306974-63-0
|
Fatty acids, C18-unsatd.,dimers, 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino] ethyl esters
|
85
|
306975-56-4
|
Propanoic acid, 3-hydroxy-2- (hydroxymethyl)-2-methyl-, polymer with 2-ethyl-2-(hydroxymethyl)-1,3-propanediol and N,N',2-tris(6-
isocyanatohexyl)imidodicarbonic diamide, reaction products with N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-1-
octanesulphonamide and N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,7-pentadecafluoro-N-(2-hydroxyethyl)-1-heptanesulphonamide, compounds with triethylamine
|
86
|
306975-57-5
|
Propanoic acid, 3-hydroxy-2-(hydroxymethyl)-2-methyl-, polymer with 1,1'-methylenebis[4- isocyanatobenzene] and 1,2,3-propanetriol, reaction products with N-
ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-1-octanesulphonamide and N-ethyl-1,1,2,2,3,3,4,4,5,5,6,6,7,7,7-pentadecafluoro-N-(2-
hydroxyethyl)-1-heptanesulphonamide, compounds with morpholine
|
87
|
306975-62-2
|
2-Propenoic acid, 2-methyl-, dodecyl ester, polymers with 2- [methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate and vinylidene chloride
|
88
|
306975-84-8
|
Poly(oxy-1,2-ethanediyl), .alpha.-hydro-.omega.-hydroxy-, polymer with 1,6-diisocyanatohexane, N-(hydroxyethyl)-N-methyl perfluoro C4-8-alkane sulphonamides-blocked
|
89
|
306975-85-9
|
2-Propenoic acid, 2-methyl-, dodecyl ester, polymers with N-(hydroxymethyl)-2-propenamide, 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl methacrylate, stearyl methacrylate and vinylidene chloride
|
90
|
306976-25-0
|
1-Hexadecanaminium, N,N-dimethyl-N-[2-[(2-methyl-1-oxo-2-propenyl)oxy]ethyl]-, bromide, polymers with Bu acrylate, Bu methacrylate and 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate
|
91
|
306976-55-6
|
2-Propenoic acid, 2-methyl-, 2-methylpropyl ester, polymer with 2,4-diisocyanato-1-methylbenzene, 2-ethyl-2-(hydroxymethyl)-1,3-propanediol and 2-propenoic acid, N-ethyl-N-(hydroxyethyl)perfluoro-C4-8-alkanesulphonamides-blocked
|
92
|
306977-58-2
|
2-Propenoic acid, 2-methyl-, 3-(trimethoxysilyl)propyl ester, polymers with acrylic acid, 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate and propylene glycol monoacrylate, hydrolysed, compounds with 2,2'-(methylimino)bis[ethanol]
|
93
|
306978-04-1
|
2-Propenoic acid, butyl ester, polymers with acrylamide, 2-[methyl[(perfluoro-C4-8-alkyl)sulphonyl]amino]ethyl acrylate and vinylidene chloride
|
94
|
306978-65-4
|
Hexane, 1,6-diisocyanato-, homopolymer, N-(hydroxyethyl)-N-methyl perfluoro-C4-8-alkane sulphonamides- and stearyl alc.-blocked
|
95
|
306979-40-8
|
Poly(oxy-1,2-ethanediyl), .alpha.-[2-(methylamino)ethyl]-.omega.-[(1,1,3,3-tetramethylbutyl)phenoxy]-, N-[(perfluoro-C4-8-alkyl)sulphonyl]
|
96
|
306980-27-8
|
Sulphonamides, C4-8-alkane, perfluoro, N,N'-[1,6-hexanediylbis[(2-oxo-3,5-oxazolidinediyl)methylene]]bis[N-methyl-
|
Източници: US EPA (2002a); US EPA (2002b); Environment Agency (2001); Consultation with Environment Canada (note that RPA reviewed a confidential draft list of PFOS precursors that was provided by Environment Canada. This was developed from the 182 PFAS that were listed in a June 2000 survey to Canadian industry (Environment Canada, 2000).
|
Приложение № 3: Алтернативи за заместване на PFOS
Сподели с приятели: |
